Seven-Membered Cyclic Diamidoalumanyls of Heavier Alkali Metals: Structures and C-H Activation of Arenes
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Like the previously reported potassium-based system, rubidium and cesium reduction of [{SiNDipp}AlI] ({SiNDipp} = {CH2SiMe2NDipp}2) with the heavier alkali metals [M = Rb and Cs] provides dimeric group 1 alumanyl derivatives, [{SiNDipp}AlM]2. In contrast, simi... ...
