Synthesis, crystal structure and thermal behavior of tetra-kis-(3-cyano-pyridine N-oxide-κ O)bis-(thio-cyanato-κ N)cobalt(II), which shows strong pseudo-symmetry
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The title compound, [Co(SCN)2(C6H4N2O)4], was prepared by the reaction of cobalt(II)thio-cyanate with 3-cyano-pyridine N-oxide in ethanol. In the crystal, the cobalt(II) cations are octa-hedrally coordinated by two terminal N-bonded thio-cyanate anions and fou... ...
