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Synthesis, crystal structure and Hirshfeld surface analysis of bis-(caffeinium) hexa-chlorido-platinum(IV) in comparison with some related compounds

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The mol-ecular and crystal structure of the title compound, (C8H11N4O2)2[PtCl6], synthesized from hexa-chloro-platinic acid and caffeine in methanol, was studied by single-crystal X-ray diffraction. The caffeinium cations form a double layer via hydrogen bonds... ...