Visible-Light-Induced Cationic Polymerization of Isobutylene: A Route toward the Synthesis of End-Functional Polyisobutylene
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The visible-light-induced cationic polymerization of isobutylene with a dimanganese decacarbonyl (Mn2(CO)10)/diphenyl iodonium hexafluorophosphate (Ph2I+PF6-) photoinitiating system in a CH2Cl2/n-hexane mixture at -30 °C was reported. It was shown that polyme... ...