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Synthesis, crystal structure and thermal decomposition pathway of bis-(iso-seleno-cyanato-κ N)tetra-kis-(pyridine-κ N)manganese(II)

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The reaction of MnCl2·2H2O with KSeCN and pyridine in water leads to the formation of the title complex, [Mn(NCSe)2(C5H5N)4], which is isotypic to its Fe, Co, Ni, Zn and Cd analogues. In its crystal structure, discrete complexes are observed that are located ... ...