Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)2+ cation and the benzene-1,3,5-tri-carboxyl-ate linker
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The asymmetric unit of catena-poly[[[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ4 N 1,N 4,N 8,N 11)nickel(II)]-μ2-5-carb-oxy-benzene-1,3-di-carboxyl-ato-κ2 O 1:O 3] octa-hydrate], {[Ni(C9H4O6)(C10H24N4)]·8H2O} n (I), consists of a macrocyclic Ni2+ cation, a c... ...