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Bis(μ4-adamantane-1,3-di-carboxyl-ato-1κ O 1:2κ O 1':3κ O 3:4κ O 3')octa-carbonyl-1κ2 C,2κ2 C,3κ2 C,4κ2 C-tetra-kis-[tris-(4-methyl-phen-yl)phosphane]-1κ P,2κ P,3κ P,4κ P-tetra-osmium(I)(2 Os- Os)

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The title complex, [{Os2(CO)4(C21H21P)2}2(C12H14O4)2], is a centrosymmetric mol-ecular loop consisting of two Os-Os sawhorse units linked by two adamantane di-carboxyl-ato bridges. It was synthesized by the microwave-mediated reaction between Os3(CO)12 and ada... ...