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Tetra-ammonium bis-(metforminium) di-μ6-oxido-tetra-μ3-oxido-tetra-deca-μ2-oxido-octa-oxidodeca-vanadium(V) hexa-hydrate

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The title compound, (NH4)4(C4H12N5)2[V10O28]·6H2O, crystallizes with the deca-vanadate anion placed on an inversion centre in space group P . This anion is surrounded by a first shell of ammonium cations and water mol-ecules, forming efficient N-H⋯O and O-H... ...