Although membrane distillation (MD) is a promising technology for water desalination and industrial wastewater treatment, the MD process is not widely applied in the global water industry due to the lack of a suitable membrane for the MD process. The design and appropriate manufacture are the most important factors for MD membrane optimization. The well-designed porous structure, superhydrophobic surface, and pore-wetting prevention of the membrane are vital properties of the MD membrane. Nowadays, electrospinning that is capable of manufacturing membranes with superhydrophobic or omni phobic properties is considered a promising technology. Electrospun nanofibrous membranes (ENMs) possess the characteristics of cylindrical morphology, re-entrant structure, and easy-shaping for a specific purpose, benefiting the membrane design and modification. Based on that, this review investigates the current state and future progress of the superhydrophobic, multi-layer, and omniphobic ENMs manufactured with various structural designs for seawater desalination and wastewater purification. We expect that this paper will provide some recommendations and guidance for further fabrication research and the configuration design of ENMs in the MD process for seawater desalination and wastewater purification.

Keywords: Electrospun nanofibrous membranes; Membrane distillation; Omniphobic; Structural design; Superhydrophobic.

© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.