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New insight into the mechanism of Pt(0)-catalyzed hydrosilylation reaction of (CH3)3SiH with CH2CHSi(CH3)3

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The non-catalytic hydrosilylation reaction has much high activation energy due to large differences in the energy of HOMO-LUMO pairing and restriction of the orbital symmetry overlap. For Pt(0)-catalytic hydrosilylation, the electronic structure of Me3SiH has ... ...