Catalytic mechanism and endo-to- exo selectivity reversion of an octalin-forming natural Diels-Alderase
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We have previously reported the identification of CghA, a proposed Diels-Alderase responsible for the formation of the bicyclic octalin core of the fungal secondary metabolite Sch210972. Here we show the crystal structure of the CghA-product complex at a resol... ...
