Syntheses, crystal structures and properties of tetra-kis-(3-methyl-pyridine-κ N)bis-(iso-thio-cyanato-κ N)manganese(II) and tetra-kis-(3-methyl-pyridine-κ N)bis-(iso-thio-cyanato-κ N)iron(II)
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The reaction of Mn(NCS)2 or Fe(NCS)2 with 3-methyl-pyridine (C6H7N) leads to the formation of two isostructural compounds with compositions [Mn(NCS)2(C6H7N)4] (1) and [Fe(NCS)2(C6H7N)4] (2). IR spectroscopic investigations indicate that only terminally coordin... ...
