Assembly of a Dihydrideborate and Two Aryl Nitriles to Form a C,N,N'-Pincer Ligand Coordinated to Osmium
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The C,N,N'-donor aryl-diimineborate pincer ligand of the complexes OsH2{κ3-C,N,N-[C6H3RCH=NB(cat)N=CHC6H4R]}(PiPr3)2 (R = H, Me) has been generated in a one-pot procedure, by the reaction of the hexahydride OsH6(PiPr3)2 with catecholborane (catBH) and two mol... ...
