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Highly Polarized Alkenes as Organocatalysts for the Polymerization of Lactones and Trimethylene Carbonate

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In this work, the activity of N-heterocyclic olefins (NHOs), a newly emerging class of organopolymerization catalyst, is investigated to affect the metal-free polymerization of lactones and trimethylene carbonate (TMC). A decisive structure-activity relationsh... ...