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Skeleton Carbonylation of Conjugated Microporous Polymers by Osmium Catalysis for Amine-Rich Functionalization

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This work introduces a new efficient method for the postsynthetic modification of conjugated microporous polymers (CMPs). Osmium catalysis of hollow CMP (H-CMP) in the presence of NaClO3 resulted in the conversion of alkynes in the skeleton of CMPs to dicarbon... ...