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Dynamics of a Supercooled Disordered Sphere-Forming Diblock Copolymer as Determined by X-ray Photon Correlation and Dynamic Mechanical Spectroscopies

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We report the dynamic behavior of a sphere-forming poly(styrene)-block-poly(1,4-butadiene) (PS-PB) diblock copolymer comprising 20 vol % PB below the order-disorder transition temperature (TODT = 153 °C) using dynamic mechanical spectroscopy (DMS) and X-ray p... ...