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Deacylation-Aided C─H Alkylative Annulation through C─C Cleavage of Unstrained Ketones

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Arene- and heteroarene-fused rings are pervasive in biologically active molecules. Direct annulation between a C─H bond on the aromatic core and a tethered alkyl moiety provides a straightforward approach to access these scaffolds; however, such a strategy is... ...