Crystal structure of μ3-tetra-thio-anti-monato-tris[(cyclam)zinc(II)] tetra-thio-anti-monate aceto-nitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetra-aza-cyclo-tetra-deca-ne)
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Reaction of Zn(ClO4)2·6H2O with cyclam (cyclam = 1,4,8,11-tetra-aza-cyclo-tetra-decane, C10H24N4) and Na3SbS4 in an aceto-nitrile/water mixture led to the formation of crystals of the title compound, [Zn3(SbS4)(C10H24N4)3](SbS4)·2CH3CN·2H2O or [(Zn-cyclam)3... ...