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Substituent Effects Provide Access to Tetrasubstituted Ring-Opening Olefin Metathesis of Bicyclo[4.2.0]oct-6-enes

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Herein, we report the origin of unexpected reactivity of bicyclo[4.2.0]oct-6-ene substrates containing an α,β-unsaturated amide moiety in ruthenium-catalyzed alternating ring-opening metathesis polymerization reactions. Specifically, compared with control su... ...