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Mechanistic Studies of Pd(II)-Catalyzed E/ Z Isomerization of Unactivated Alkenes: Evidence for a Monometallic Nucleopalladation Pathway

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Pd(II)-catalyzed E/Z isomerization of alkenes is a common process-yet its mechanism remains largely uncharacterized, particularly with non-conjugated alkenes. In this work, the mechanism of Pd(II)-catalyzed E/Z isomerization of unactivated olefins containing a... ...