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Elucidating the Mechanism of Ambient-Temperature Aldol Condensation of Acetaldehyde on Ceria

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Using in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and density functional theory (DFT) calculations, we conclusively demonstrate that acetaldehyde (AcH) undergoes aldol condensation when flown over ceria octahedral nanoparticles... ...