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Alkali Metal Ion-exchange in a Metal-Organic Framework Based on Lanthanum and 1,4-Phenylenebis(methylidyne)tetrakis(phosphonic acid)

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The ion-exchange selectivity of four metal-organic frameworks (denoted as MLaL), formed by alkali metal ions (M+), La3+, and 1,4-phenylenebis(methylidyne)tetrakis(phosphonic acid) (L), was examined. Unusual selectivity for the alkali metal ions was observed, w... ...