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Rovibrational spectroscopy of the CH+-He and CH+-He4 complexes

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A cryogenic 22-pole ion trap apparatus is used in combination with a table-top pulsed IR source to probe weakly bound CH+-He and CH+-He4 complexes by predissociation spectroscopy at 4 K. The infrared photodissociation spectra of the C-H stretching vibrations a... ...