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Copper(II) Coordination Compounds with Methanoato and Pyridine Ligands: Conversion from Mononuclear to Polynuclear in the Presence of Moisture

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Blue prismatic crystals of mononuclear [CuII(O2CH)2(Py)3] (Py = pyridine, C5H5N), 1, were prepared from reaction solution containing dry pyridine and dinuclear [Cu2II(O2CH)4(Py)2]. When a portion of solution together with crystals was exposed to air moisture, ... ...