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Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

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The synthesis and organometallic chemistry of rhodium(I) complex [Rh(CNC-Me)(SOMe2)][BArF 4], featuring NHC-based pincer and labile dimethyl sulfoxide ligands, is reported. This complex reacts with biphenylene and chlorobenzene to afford products resulting fro... ...