Heterometallic Copper-Vanadium Compounds: Crystal Structures of Polymers [Cu(im)4(V2O4(mand)2)] n and [Cu(im)4(V2O4((S)- mand)2)] n ·2 n H2O (im = imidazole, mand = mandelato2-)
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Abstract: Two new 1D polymeric heterometallic copper-vanadium compounds were prepared. The polymers are constructed from [Cu(im)4]2+ cations that are coordinated to two terminal oxido ligands of [V2O4(mand)2]2- anions. The strong... ...