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Providing a New Aniline Bioisostere through the Photochemical Production of 1-Aminonorbornanes

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This report describes the photochemical conversion of aminocyclopropanes into 1-aminonorbornanes via formal [3+2] cycloadditions initiated by homolytic fragmentation of amine radical cation intermediates. Aligning with the modern movement toward sp 3 -rich mot... ...