Making an order: the concerted alignment of [MOF5]2- (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II)
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Electronic distortions, which are inherent in the oxide fluoride anions [MOF5]2- (M = Nb and Ta), provide an origin of polar molecular arrangements for the development of new polar second-harmonic-generating, piezo-, pyro- and ferroelectric materials. It is st... ...
