Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates
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Allenylsilanolates can undergo cross-coupling at the α- or γ-terminus, and site selectivity appears to be determined by the intrinsic transmetalation mechanism. Fine-tuning of concentration, nucleophilicity, and steric bulk of the silanolate moiety allows fo... ...
