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Calixarene-Mediated Synthesis of Cobalt Nanoparticles: An Accretion Model for Separate Control over Nucleation and Growth

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The nucleation and growth of crystalline cobalt nanoparticles (Co NPs) under solvothermal conditions can be separated into distinct stages by using (i) polynuclear clusters with multivalent capping ligands to initiate nucleation, and (ii) thermolabile organome... ...