Stereocontrolled 1- S-glycosylation and comparative binding studies of photoprobe-thiosaccharide conjugates with their O-linked analogs
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The use of thioglycosides and other glycan derivatives with anomeric sulfur linkages is gaining increasing interest, both in synthesis and in various biological contexts. Herein, we demonstrate the occurrence and circumvention of anomerization during 1-S-glyco... ...
