Dissecting Anion Effects in Gold(I)-Catalyzed Intermolecular Cycloadditions
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From a series of gold complexes of the type [t-BuXPhosAu(MeCN)]X (X=anion), the best results in intermolecular gold(I)-catalyzed reactions are obtained with the complex with the bulky and soft anion BAr4F- [BAr4F-=3,5-bis(trifluoromethyl)phenylborate] improvin... ...
