Synthesis, Characterization, and Catalytic Activity of Ni(II) Alkyl Complexes Supported by Pyrrole-Diphosphine Ligands
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The organometallic Ni(II) chemistry of the pyrrole-based pincer ligands, (P2RPyr)- (P2RPyr = 2,5-(R2PCH2)2C4H2N, R = Ph or Cy) is reported. Reactions of Grignard reagents with [NiCl(P2R Pyr)] afford a variety of alkyl and aryl complexes (methyl, ethyl, benzyl,... ...
