Intramolecular Arene C-H to C-P Functionalization Mediated by Ni(II) and Pd(II)
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A trisphosphine ligand with a triarylbenzene backbone was employed to support mono-nickel(II) and palladium(II) complexes. Two phosphine arms coordinated to the metal center, while the third phosphine was found to form a C-P bond with dearomatization of the ce... ...