Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane
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Reversible, heterolytic addition of H2 across an iron-boron bond in a ferraboratrane with formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These compounds catalyze the hydrogenation of alkenes and alkynes to the respective alkanes... ...
