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A spectroscopic and computational study of Al(III) complexes in cryolite melts: Effect of cation nature

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Lithium, sodium and potassium cryolite melts are probed by Raman spectroscopy in a wide range of the melt composition. The experimental data demonstrate a slight red shift of main peaks and a decrease of their half-widths in the row Li(+), Na(+), K(+). Quantum... ...