Synthesis of Block Copolymers of Varying Architecture Through Suppression of Transesterification during Coordinated Anionic Ring Opening Polymerization
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Well-defined di- and triblock copolymers consisting of ε-caprolactone (CL), L-lactide (LA), and trimethylene carbonate (TMC) were synthesized via "PLA first route" in coordinated anionic ring opening polymerization/copolymerization (CAROP) with tin (II) octoa... ...
