N-Heterocyclic Carbene Bound Nickel(I) Complexes and Their Roles in Catalysis
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New paramagnetic Ni(I)(IMes)(2)X (IMes: 1,3-bis-(2,4,6-trimethylphenyl)-imidazol-2-ylidene) were prepared from the reaction of Ni(IMes)(2) with aryl halides. Products that would arise from oxidative addition were not observed. In contrast, Ni(II)(tmiy)(2)(X)(A... ...
