Synthesis of a Benzodiazepine-derived Rhodium NHC Complex by C-H Bond Activation
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The synthesis and characterization of a Rh(I)-NHC complex generated by C-H activation of 1,4-benzodiazepine heterocycle are reported. This complex constitutes a rare example of a carbene tautomer of a 1,4-benzodiazepine aldimine stabilized by transition metal ... ...
