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Unexpected C(carbene)-X (X: I, Br, Cl) Reductive Elimination From N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions

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The non-innocent behaviors of NHC ligands have attracted wide attention due to their important implications for catalyst designs and reaction mechanisms. Herein, we report facile C(carbene)-halogen reductive eliminations from NHC copper halide complexes at RT ... ...