Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the beta-Diketiminato Ligand
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Synthesis of the complex (BDI)Nb(N(t)Bu)Cl(2)py (BDI = HC[C(Me)N(2,6-iPr(2)-C(6)H(3))](2)) was achieved in high yield following the treatment of Nb(N(t)Bu)Cl(3)py(2) with Li(BDI)(OEt(2)). Substitution of the chlorides for fluorides was effected by introducing ... ...