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Monoclinic M(B) phase and phase instability in [110] field cooled Pb(Zn(13)Nb(23))O(3)-4.5%PbTiO(3) single crystals

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We report the finding of a monoclinic M(B) phase in Pb(Zn(13)Nb(23))O(3)-4.5%PbTiO(3) single crystals. High precision x-ray diffraction investigations of [110] field cooled crystals have shown a transformation sequence of cubic(C)-->tetragonal(T)-->orthorhombi... ...