Progress in homogeneous catalysis depends upon an understanding of the reaction mechanism; in asymmetric catalysis this entails an insight into the origins of enantioselectivity. Significant advances have been made in the area of alkene reduction catalyzed by rhodium or ruthenium complexes, which has been in tandem with the development of new, more effective ligands for the reaction. The combination of quantum chemical calculations and direct spectroscopic observation of catalytic intermediates has proved powerful in this regard.
Current opinion in drug discovery & development. 2000 Nov;3(6):825-32.
New mechanistic aspects of the asymmetric homogeneous hydrogenation of alkenes
烯烃手性均相氢化的若干新进展 翻译改进
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PMID: 19649910
摘要 Ai翻译
Keywords：alkenes; mechanistic aspects
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