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Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions

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The synthesis and reactivity of dibenzyl cationic tantalum imido complexes is described. The trialkyl tantalum imido compounds Bn(3)Ta=NCMe(3) (1) and Np(3)Ta=NCMe(3) (2) were synthesized as starting materials for the study of dialkyl cationic tantalum imido c... ...