Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination
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In situ combination of diphosphinic amides and Zr(NMe(2))(4) results in the formation of chiral zirconium bis(amido) complexes. The complexes are competent catalysts for intramolecular asymmetric alkene hydroamintion, providing piperidines and pyrrolidines in ... ...