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The journal of physical chemistry. A. 2008 Jul 3;112(26):5858-65. doi: 10.1021/jp802655f Q22.82025

Charged states of Sc3N@C68: an in situ spectroelectrochemical study of the radical cation and radical anion of a non-IPR fullerene

非IPR富勒烯Sc3N@C68的阴阳离子物种的原位谱学电化学研究 翻译改进

Peter Rapta  1, Alexey A Popov, Shangfeng Yang, Lothar Dunsch

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  • 1 Group of Electrochemistry and Conducting Polymers, Leibniz-Institute for Solid State and Materials Research Dresden, D-01171 Dresden, Germany.
  • DOI: 10.1021/jp802655f PMID: 18543891

    摘要 Ai翻译

    The redox behavior of Sc 3N@C 68 is studied systematically by means of electrochemistry, in situ ESR/Vis-NIR spectroelectrochemistry, and detailed theoretical treatment. Formation of the negatively and positively charged paramagnetic species for the same trimetallic nitride endohedral fullerene is demonstrated for the first time. The electrochemical study of Sc 3N@C 68 exhibits two electrochemically irreversible but chemically reversible reduction steps an... ...点击完成人机验证后继续浏览
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    期刊名:Journal of physical chemistry a

    缩写:J PHYS CHEM A

    ISSN:1089-5639

    e-ISSN:1520-5215

    IF/分区:2.8/Q2

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    Charged states of Sc3N@C68: an in situ spectroelectrochemical study of the radical cation and radical anion of a non-IPR fullerene