On the crystal chemistry of olivine-type germanate compounds, Ca1 + xM1 - xGeO4 (M2+ = Ca, Mg, Co, Mn)
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Germanate compounds, CaMGeO(4) with M(2+) = Ca, Mg, Co and Mn, were synthesized as single crystals by slow cooling from the melt or by flux growth techniques. All the compositions investigated exhibit Pnma symmetry at 298 K and adopt the olivine structure. The... ...
