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Hartwig-Buchwald amination on solid supports: a novel access to a diverse set of 1H-benzotriazoles

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Hartwig-Buchwald amination reactions of bromo- and chloroarenes were performed on solid supports with triazene-linked arenes. Immobilized 2-haloarenes were treated with diverse primary amines and anilines at 100 degrees C under palladium catalysis to yield N-s... ...