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Halogen...halogen interactions in pressure-frozen ortho- and meta-dichlorobenzene isomers

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Isomers 1,2-dichlorobenzene (o-DCB) and 1,3-dichlorobenzene (m-DCB) were high-pressure frozen in-situ in a Merrill-Bassett diamond-anvil cell and their structures determined at room temperature and at 0.18 (5) GPa for o-DCB, and 0.17 (5) GPa for m-DCB by singl... ...