Verification of the interaction of a tryparedoxin peroxidase with tryparedoxin by ESI-MS/MS
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Tryparedoxin peroxidases (TXNPx) catalyze hydroperoxide reduction by tryparedoxin (TXN) by an enzyme substitution mechanism presumed to involve three catalytic intermediates: (i) a transient oxidation state having C52 oxidized to a sulfenic acid, (ii) the stab... ...
